In a large bowl, combine the vinegar, garlic, tex-mex spices, and salt. Add the meat and toss to coat, rubbing thoroughly. Cover and refrigerate from 1 to 48 hours.
Remove the meat from the refrigerator and let temper for 1 hour before cooking.
With the rack in the middle position, preheat the oven or grill to 140 °C (300 °F).
Place the pork chops, side by side, on a baking sheet. Bake or grill, closed for 2 hours and 30 minutes to 3 hours or until the meat is tender.
In a small bowl, combine the ketchup, mustard, and honey. Brush on the pork chops and cook for about 45 minutes.
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