With the rack in the middle position, preheat the oven to 180°C (350°F). Generously butter a 2.5-litre (10-cup) Bundt cake pan or other tube pan.
In a bowl, combine the pears, rum and vanilla. Let macerate for about 10 minutes.
In a second bowl, combine the flour, baking powder and salt. Set aside.
In another bowl, cream the butter and sugar using an electric mixer. Add the eggs one at a time, beating until smooth.
With the mixer on low speed, add the dry ingredients, alternating with the sour cream. Using a spatula, gently fold in the pear and chocolate mixture. Scrape the batter into the pan. Bake until a toothpick inserted in the centre comes out clean, about 1 hour, 20 minutes. Let cool. Unmould and cool completely on a cake rack. Set aside on a cookie sheet.
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